Copolymerization of Vinyl Chloride with Higher Alkyl Vinyl Ethers in Emulsion
نویسندگان
چکیده
منابع مشابه
Copolymerization of Vinyl Chloride by Organometallic Compounds
ABSTRACT The copolymerizations of vinyl chloride with o-olefin or acrylic compounds were investigated with organometallic compounds as catalysts. In general, organoaluminium compounds need to be treated with a complexing agent such as tetrahydrofuran prior to use. Otherwise the former reacts with polyvinyl chloride and loses its activity. The copolymer of vinyl chloride and propylene was thus o...
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Since the advent of Ziegler-Natta polymerization of ethylene, attempts have been made to extend coordination polymerization to commercially important monomers with polar functionality. In this study we examined the copolymerization of perdeuterated vinyl chloride (VC) and perdeuterated vinyl acetate (VA) with ethylene using a tridentate Fe(II) dichloride pyridine diimine metal catalyst. The res...
متن کاملRelative Reactivities in Vinyl Copolymerization
Synopsis. From data in the literature on relatine rates of copolymerization it has been possible to evaluute two constants, Q and e , cheracteristic of a n individual monomer, which appear to account satisfactorily .for its behavior in copolymerization. The constant Q describes the “general monomer reactivity” and is apparently related to possibilities for stabilization in a radical adduct. The...
متن کاملWorker exposure to vinyl chloride and poly(vinyl chloride).
The National Institute for Occupational Safety and Health (NIOSH) in early 1974 began industrial hygiene studies of vinyl chloride exposed workers. Three VC monomer plants, three VC polymerization plants, and seven PVC fabrication plants were surveyed. V polymerization plant workers and workers in one job category in VC monomer plants were exposed to average levels above 1 ppm. The highest aver...
متن کاملMiniemulsion Copolymerization of Ethylene and Vinyl Acetate
The copolymerizations of a gaseous monomer (ethylene) and a liquid monomer (vinyl acetate) via emulsion and miniemulsion polymerizations are reported. Reactions in which the vinyl acetate was introduced in both batch and semibatch modes are carried out. (Ethylene introduction is always in a semibatch model since the polymerization is carried out under a constant pressure of ethylene in the reac...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1960
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.63.10_1798